Titulo:
STEP-BY-STEP CALCULATION OF REACTIVE EXTRACTION CASCADES APPLYING THE EQUILIBRIUM MODEL
.
Sumario:
This paper presents a step-by-step calculation algorithm for reactive extraction cascade simulation. The theoretical basis is taken from reactive liquid-liquid equilibrium thermodynamics. This method can be applied to parallel, countercurrent, and cross-current arrangements, operating with the most important practical specifications: splitting of solvent and feed streams, location of reaction zone, choice of feed points, and specification of transferred heat flow. To illustrate the usefulness of this approach, reactive extraction technological schemes for the synthesis of n-amyl acetate from aqueous acetic acid solutions were simulated. Although the examples are designed to prove algorithm adequacy, it was also found that the n-amyl acetate... Ver más
Guardado en:
1794-1237
2463-0950
11
2014-10-17
185
201
info:eu-repo/semantics/openAccess
http://purl.org/coar/access_right/c_abf2
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metarevistapublica_eia_revistaeia_englishversion_8_article_932 |
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ojs |
| spelling |
STEP-BY-STEP CALCULATION OF REACTIVE EXTRACTION CASCADES APPLYING THE EQUILIBRIUM MODEL STEP-BY-STEP CALCULATION OF REACTIVE EXTRACTION CASCADES APPLYING THE EQUILIBRIUM MODEL This paper presents a step-by-step calculation algorithm for reactive extraction cascade simulation. The theoretical basis is taken from reactive liquid-liquid equilibrium thermodynamics. This method can be applied to parallel, countercurrent, and cross-current arrangements, operating with the most important practical specifications: splitting of solvent and feed streams, location of reaction zone, choice of feed points, and specification of transferred heat flow. To illustrate the usefulness of this approach, reactive extraction technological schemes for the synthesis of n-amyl acetate from aqueous acetic acid solutions were simulated. Although the examples are designed to prove algorithm adequacy, it was also found that the n-amyl acetate production by reactive extraction has strong limitations on conversion and separation. In addition, it is not an interesting alternative to increase the economic value of acetic acid and water streams. Prieto Ríos, Luis Gabriel Arturo Calvache, Jaime Eduardo Sánchez Correa, César Augusto Reactive extraction Reactive liquid-liquid equilibrium Esterification systems N-amyl acetate step-by-step calculation algorithm. 11 21 Artículo de revista Journal article 2014-10-17 00:00:00 2014-10-17 00:00:00 2014-10-17 application/pdf Revista EIA / English version Revista EIA / English version 1794-1237 2463-0950 https://revistas.eia.edu.co/index.php/Reveiaenglish/article/view/932 https://revistas.eia.edu.co/index.php/Reveiaenglish/article/view/932 spa https://creativecommons.org/licenses/by-nc-sa/4.0/ 185 201 https://revistas.eia.edu.co/index.php/Reveiaenglish/article/download/932/842 info:eu-repo/semantics/article http://purl.org/coar/resource_type/c_6501 http://purl.org/redcol/resource_type/ARTREF info:eu-repo/semantics/publishedVersion http://purl.org/coar/version/c_970fb48d4fbd8a85 info:eu-repo/semantics/openAccess http://purl.org/coar/access_right/c_abf2 Text Publication |
| institution |
UNIVERSIDAD EIA |
| thumbnail |
https://nuevo.metarevistas.org/UNIVERSIDADEIA/logo.png |
| country_str |
Colombia |
| collection |
Revista EIA / English version |
| title |
STEP-BY-STEP CALCULATION OF REACTIVE EXTRACTION CASCADES APPLYING THE EQUILIBRIUM MODEL |
| spellingShingle |
STEP-BY-STEP CALCULATION OF REACTIVE EXTRACTION CASCADES APPLYING THE EQUILIBRIUM MODEL Prieto Ríos, Luis Gabriel Arturo Calvache, Jaime Eduardo Sánchez Correa, César Augusto Reactive extraction Reactive liquid-liquid equilibrium Esterification systems N-amyl acetate step-by-step calculation algorithm. |
| title_short |
STEP-BY-STEP CALCULATION OF REACTIVE EXTRACTION CASCADES APPLYING THE EQUILIBRIUM MODEL |
| title_full |
STEP-BY-STEP CALCULATION OF REACTIVE EXTRACTION CASCADES APPLYING THE EQUILIBRIUM MODEL |
| title_fullStr |
STEP-BY-STEP CALCULATION OF REACTIVE EXTRACTION CASCADES APPLYING THE EQUILIBRIUM MODEL |
| title_full_unstemmed |
STEP-BY-STEP CALCULATION OF REACTIVE EXTRACTION CASCADES APPLYING THE EQUILIBRIUM MODEL |
| title_sort |
step-by-step calculation of reactive extraction cascades applying the equilibrium model |
| description |
This paper presents a step-by-step calculation algorithm for reactive extraction cascade simulation. The theoretical basis is taken from reactive liquid-liquid equilibrium thermodynamics. This method can be applied to parallel, countercurrent, and cross-current arrangements, operating with the most important practical specifications: splitting of solvent and feed streams, location of reaction zone, choice of feed points, and specification of transferred heat flow. To illustrate the usefulness of this approach, reactive extraction technological schemes for the synthesis of n-amyl acetate from aqueous acetic acid solutions were simulated. Although the examples are designed to prove algorithm adequacy, it was also found that the n-amyl acetate production by reactive extraction has strong limitations on conversion and separation. In addition, it is not an interesting alternative to increase the economic value of acetic acid and water streams.
|
| author |
Prieto Ríos, Luis Gabriel Arturo Calvache, Jaime Eduardo Sánchez Correa, César Augusto |
| author_facet |
Prieto Ríos, Luis Gabriel Arturo Calvache, Jaime Eduardo Sánchez Correa, César Augusto |
| topicspa_str_mv |
Reactive extraction Reactive liquid-liquid equilibrium Esterification systems N-amyl acetate step-by-step calculation algorithm. |
| topic |
Reactive extraction Reactive liquid-liquid equilibrium Esterification systems N-amyl acetate step-by-step calculation algorithm. |
| topic_facet |
Reactive extraction Reactive liquid-liquid equilibrium Esterification systems N-amyl acetate step-by-step calculation algorithm. |
| citationvolume |
11 |
| citationissue |
21 |
| publisher |
Revista EIA / English version |
| ispartofjournal |
Revista EIA / English version |
| source |
https://revistas.eia.edu.co/index.php/Reveiaenglish/article/view/932 |
| language |
spa |
| format |
Article |
| rights |
https://creativecommons.org/licenses/by-nc-sa/4.0/ info:eu-repo/semantics/openAccess http://purl.org/coar/access_right/c_abf2 |
| type_driver |
info:eu-repo/semantics/article |
| type_coar |
http://purl.org/coar/resource_type/c_6501 |
| type_version |
info:eu-repo/semantics/publishedVersion |
| type_coarversion |
http://purl.org/coar/version/c_970fb48d4fbd8a85 |
| type_content |
Text |
| publishDate |
2014-10-17 |
| date_accessioned |
2014-10-17 00:00:00 |
| date_available |
2014-10-17 00:00:00 |
| url |
https://revistas.eia.edu.co/index.php/Reveiaenglish/article/view/932 |
| url_doi |
https://revistas.eia.edu.co/index.php/Reveiaenglish/article/view/932 |
| issn |
1794-1237 |
| eissn |
2463-0950 |
| citationstartpage |
185 |
| citationendpage |
201 |
| url2_str_mv |
https://revistas.eia.edu.co/index.php/Reveiaenglish/article/download/932/842 |
| _version_ |
1811200279739105280 |